Yes, I am agree with Blackhawk-17, I am also having multiple instance, and got PID in errorlog file
In my case there is two instance
For first instance
Path for errorlog file is "Program Files\Microsoft SQL Server\MSSQL.1\MSSQL\LOG"
For Second instance
Path for errorlog file is "Program Files\Microsoft SQL Server\MSSQL.3\MSSQL\LOG"
You can Open it with NotePad.
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